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Abstract Ground-based high-resolution cross-correlation spectroscopy (HRCCS;R ≳ 15,000) is a powerful complement to space-based studies of exoplanet atmospheres. By resolving individual spectral lines, HRCCS can precisely measure chemical abundance ratios, directly constrain atmospheric dynamics, and robustly probe multidimensional physics. But the subtleties of HRCCS data sets—e.g., the lack of exoplanetary spectra visible by eye and the statistically complex process of telluric removal—can make interpreting them difficult. In this work, we seek to clarify the uncertainty budget of HRCCS with a forward-modeling approach. We present an HRCCS observation simulator,scope,⁵⁵https://github.com/arjunsavel/scopethat incorporates spectral contributions from the exoplanet, star, tellurics, and instrument. This tool allows us to control the underlying data set, enabling controlled experimentation with complex HRCCS methods. Simulating a fiducial hot Jupiter data set (WASP-77Ab emission with IGRINS), we first confirm via multiple tests that the commonly used principal component analysis does not bias the planetary signal when few components are used. Furthermore, we demonstrate that mildly varying tellurics and moderate wavelength solution errors induce only mild decreases in HRCCS detection significance. However, limiting-case, strongly varying tellurics can bias the retrieved velocities and gas abundances. Additionally, in the low signal-to-noise ratio limit, constraints on gas abundances become highly non-Gaussian. Our investigation of the uncertainties and potential biases inherent in HRCCS data analysis enables greater confidence in scientific results from this maturing method. 

Abstract A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet’s initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultrahot Jupiter WASP-121 b using the high-resolution (R= 45,000) IGRINS instrument on Gemini South. Probing the planet’s direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly superstellar C/O ratio of ${0.70}_{-0.10}^{+0.07}$and a moderately superstellar refractory-to-volatile ratio at ${3.83}_{-1.67}^{+3.62}\times$stellar. This combination is most consistent with formation between the soot line and H₂O snow line, but we cannot rule out formation between the H₂O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H₂O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet dayside. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high-resolution spectroscopy in the near-IRHandKbands. 

Abstract Measurements of the carbon-to-oxygen (C/O) ratios of exoplanet atmospheres can reveal details about their formation and evolution. Recently, high-resolution cross-correlation analysis has emerged as a method of precisely constraining the C/O ratios of hot Jupiter atmospheres. We present two transits of the ultrahot Jupiter WASP-76b observed between 1.4 and 2.4μm with the high-resolution Immersion GRating INfrared Spectrometer on the Gemini-S telescope. We detected the presence of H₂O, CO, and OH at signal-to-noise ratios of 6.93, 6.47, and 3.90, respectively. We performed two retrievals on this data set. A free retrieval for abundances of these three species retrieved a volatile metallicity of $\left(\frac{\mathrm{C}+\mathrm{O}}{\mathrm{H}}\right)=-{0.70}_{-0.93}^{+1.27}$, consistent with the stellar value, and a supersolar carbon-to-oxygen ratio of C/O $={0.80}_{-0.11}^{+0.07}$. We also ran a chemically self-consistent grid retrieval, which agreed with the free retrieval within 1σbut favored a slightly more substellar metallicity and solar C/O ratio ( $\left(\frac{\mathrm{C}+\mathrm{O}}{\mathrm{H}}\right)=-{0.74}_{-0.17}^{+0.23}$and C/O $={0.59}_{-0.14}^{+0.13}$). A variety of formation pathways may explain the composition of WASP-76b. Additionally, we found systemic (V_sys) and Keplerian (K_p) velocity offsets which were broadly consistent with expectations from 3D general circulation models of WASP-76b, with the exception of a redshiftedV_sysfor H₂O. Future observations to measure the phase-dependent velocity offsets and limb differences at high resolution on WASP-76b will be necessary to understand the H₂O velocity shift. Finally, we find that the population of exoplanets with precisely constrained C/O ratios generally trends toward super-solar C/O ratios. More results from high-resolution observations or JWST will serve to further elucidate any population-level trends. 

Abstract Recently, the first JWST measurement of thermal emission from a rocky exoplanet was reported. The inferred dayside brightness temperature of TRAPPIST-1 b at 15 μ m is consistent with the planet having no atmosphere and therefore no mechanism by which to circulate heat to its nightside. In this Letter, we compare TRAPPIST-1 b's measured secondary eclipse depth to predictions from a suite of self-consistent radiative-convective equilibrium models in order to quantify the maximum atmospheric thickness consistent with the observation. We find that plausible atmospheres (i.e., those that contain at least 100 ppm CO 2 ) with surface pressures greater than 0.3 bar are ruled out at 3 σ , regardless of the choice of background atmosphere, and a Mars-like thin atmosphere with surface pressure 6.5 mbar composed entirely of CO 2 is also ruled out at 3 σ . Thicker atmospheres of up to 10 bar (100 bar) are consistent with the data at 1 σ (3 σ ) only if the atmosphere lacks any strong absorbers across the mid-IR wavelength range—a scenario that we deem unlikely. We additionally model the emission spectra for bare-rock planets of various compositions. We find that a basaltic, metal-rich, and Fe-oxidized surface best matches the measured eclipse depth to within 1 σ , and the best-fit gray albedo is 0.02 ± 0.11. We conclude that planned secondary eclipse observations at 12.8 μ m will serve to validate TRAPPIST-1 b's high observed brightness temperature, but are unlikely to further distinguish among the consistent atmospheric and bare-rock scenarios. 

Abstract Ground-based high-resolution and space-based low-resolution spectroscopy are the two main avenues through which transiting exoplanet atmospheres are studied. Both methods provide unique strengths and shortcomings, and combining the two can be a powerful probe into an exoplanet’s atmosphere. Within a joint atmospheric retrieval framework, we combined JWST NIRSpec/G395H secondary eclipse spectra and Gemini South/IGRINS pre- and post-eclipse thermal emission observations of the hot Jupiter WASP-77A b. Our inferences from the IGRINS and NIRSpec data sets are consistent with each other, and combining the two allows us to measure the gas abundances of H₂O and CO, as well as the vertical thermal structure, with higher precision than either data set provided individually. We confirm WASP-77A b’s subsolar metallicity ([(C+O)/H] = −0.61 ${}_{-0.09}^{+0.10})$and solar C/O ratio (C/O = 0.57 ${}_{-0.06}^{+0.06})$. The two types of data are complementary, and our abundance inferences are mostly driven by the IGRINS data, while inference of the thermal structure is driven by the NIRSpec data. Our ability to draw inferences from the post-eclipse IGRINS data is highly sensitive to the number of singular values removed in the detrending process, potentially due to high and variable humidity. We also search for signatures for atmospheric dynamics in the IGRINS data and find that propagated ephemeris error can manifest as either an orbital eccentricity or a strong equatorial jet. Neither are detected when using more up-to-date ephemerides. However, we find moderate evidence of thermal inhomogeneity and measure a cooler nightside that presents itself in the later phases after secondary eclipse. 

Abstract The characterization of young planets (<300 Myr) is pivotal for understanding planet formation and evolution. We present the 3–5μm transmission spectrum of the 17 Myr, Jupiter-size (R∼10R_⊕) planet, HIP 67522b, observed with JWST NIRSpec/G395H. To check for spot contamination, we obtain a simultaneousg-band transit with the Southern Astrophysical Research Telescope. The spectrum exhibits absorption features 30%–50% deeper than the overall depth, far larger than expected from an equivalent mature planet, and suggests that HIP 67522b’s mass is <20M_⊕irrespective of cloud cover and stellar contamination. A Bayesian retrieval analysis returns a mass constraint of 13.8 ± 1.0M_⊕. This challenges the previous classification of HIP 67522b as a hot Jupiter and instead, positions it as a precursor to the more common sub-Neptunes. With a density of <0.10 g cm⁻³, HIP 67522 b is one of the lowest-density planets known. We find strong absorption from H₂O and CO₂(≥7σ), a modest detection of CO (3.5σ), and weak detections of H₂S and SO₂(≃2σ). Comparisons with radiative-convective equilibrium models suggest supersolar atmospheric metallicities and solar-to-subsolar C/O ratios, with photochemistry further constraining the inferred atmospheric metallicity to 3 × 10 solar due to the amplitude of the SO₂feature. These results point to the formation of HIP 67522b beyond the water snowline, where its envelope was polluted by icy pebbles and planetesimals. The planet is likely experiencing substantial mass loss (0.01–0.03M_⊕Myr⁻¹), sufficient for envelope destruction within a gigayear. This highlights the dramatic evolution occurring within the first 100 Myr of its existence. 

Abstract Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures <800 K. The opacities of laboratory produced organic compounds (tholins) from Khare et al. have become a standard for modeling haze in exoplanet atmospheres. However, these tholins were grown in an oxygen-free, Titan-like environment that is very different from typical assumptions for exoplanets, where C/O ∼ 0.5. This work presents the 0.13–10 μ m complex refractive indices derived from laboratory transmission measurements of tholins grown in environments with different oxygen abundances. With the increasing uptake of oxygen, absorption increases across the entire wavelength range, and a scattering feature around 6 μ m shifts toward shorter wavelengths and becomes more peaked around 5.8 μ m, due to a C = O stretch resonance. Using GJ 1214 b as a test case, we examine the transmission spectra of a sub-Neptune planet with C/O ratios of solar, 1, and 1000 to evaluate the effective differences between our opacities and those of Khare. For an atmosphere with solar hydrogen and helium abundances, we find a difference of 200–1500 ppm, but for high-metallicity ( Z = 1000) environments, the difference may only be 20 ppm. The 1–2 μ m transmission data for GJ 1214 b rule out the Titan-like haze model, and are more consistent with C/O = 1 and C/O = solar haze models. This work demonstrates that using haze opacities that are more consistent with underlying assumptions about bulk atmospheric composition are important for building self-consistent models that appropriately constrain the atmospheric C/O ratio, even when molecular features are obscured. 

Abstract We explore terrestrial planet formation with a focus on the supply of solid-state organics as the main source of volatile carbon. For the water-poor Earth, the water ice line, or ice sublimation front, within the planet-forming disk has long been a key focal point. We posit that the soot line, the location where solid-state organics are irreversibly destroyed, is also a key location within the disk. The soot line is closer to the host star than the water snow line and overlaps with the location of the majority of detected exoplanets. In this work, we explore the ultimate atmospheric composition of a body that receives a major portion of its materials from the zone between the soot line and water ice line. We model a silicate-rich world with 0.1% and 1% carbon by mass with variable water content. We show that as a result of geochemical equilibrium, the mantle of these planets would be rich in reduced carbon but have relatively low water (hydrogen) content. Outgassing would naturally yield the ingredients for haze production when exposed to stellar UV photons in the upper atmosphere. Obscuring atmospheric hazes appear common in the exoplanetary inventory based on the presence of often featureless transmission spectra. Such hazes may be powered by the high volatile content of the underlying silicate-dominated mantle. Although this type of planet has no solar system counterpart, it should be common in the galaxy with potential impact on habitability. 

Abstract The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI Low Resolution Spectrometer observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000× solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities ≤300× solar due to their large corresponding molecular feature amplitudes, preferring values ≥1000× solar and column haze production rates ≥10 −10 g cm −2 s −1 . The steam atmosphere scenario with similarly high haze production rates also exhibits sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights ≥15 g mol −1 are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b’s atmosphere would likely require multiple transits and eclipses using JWST across the near- and mid-infrared, potentially complemented by ground-based high-resolution transmission spectroscopy.